Применим правило Лопиталя:
=
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limit( (arctan(2*x))/(3*x) , x = 0);
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af:= plot((arctan(2*x))/(3*x), x = -1..-0.01, color = red):
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bf:= plot((arctan(2*x))/(3*x), x = 0.01..1, color = red):
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cf:= plot([x,2/3,x = -0.5..0.5], color = magenta):
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display((af,bf,cf));